I've had a similar sound for years, when starting stone cold on very cold days. It lasts about 5 sec. I suspect (in my case) it is the power steering pump, because its shaft is a little loose. I'm waiting for the sound to get worse, which it has not. You can test for power steering, a/c compressor, alternator, idler by taking off your serp belt and spinning or wiggling each rotating part. This isn't proof because the part may behave differently at working speed and under load, but it could point to the problem. Again in my case, I don't suspect timing belt, waterpump, or tensioner because I replaced/attended to these and the noise has not changed one bit.
Is your serp belt dry and in top condition? You might get a squeal for a little while after starting because the alternator is initially working hard to replace at a high rate the charge in the battery you used to start the engine. Once the battery is back to near normal charge the alternator drive would stop slipping.
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