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White stuff on spark plug electrodes 200

Pulled the plugs from the '80 yesterday and I noticed that 1, 2 & 3 look normal but #4 has a white substance on the electrodes. It's not crusty or built up. It just has a white finish. The pics I have of plug conditions don't really have an example that matches this. The plug looks okay otherwise. So what is this white stuff?
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'80 DL 2 door, '89 DL Wagon







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