If the head gasket is leaking cylinder pressure into the cooling system you will see bubbles in the expansion tank when the engine is warm and running. Since the pressure cap is on the expansion tank you will need to start the car with it removed or be very careful removing it when hot (a good way to get a scalded hand...).
Also, if the head gasket is leaking between the cylinder and the cooling system you will see that one or more spark plugs is very clean, maybe with a slight green tint on the porcelain.
Greg
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